To search for available packages you can use the command pamac search. For example, to search the repos for packages containing the word smplayer:
pamac search smplayer
smplayer [Installed] 19.5.0-1 community
Media player with built-in codecs that can play virtually all video and audio formats
smplayer-skins [Installed] 1:15.2.0-2 community
Skins for SMPlayer
smplayer-themes [Installed] 1:18.6.0-1 community
Themes for SMPlayer
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